Nope - Penguin has this special edition Jane Eyre, but it's bound in cloth rather than leather; the only Penguin Titles available in leather are The Picture of Dorian Gray, The Great Gatsby, Breakfast at Tiffany's, The Big Sleep, Room with a View and Brideshead Revisited.
Between the Penguin hardback and the Fine hardback of Jane Eyre, I've already chosen the Fine - I like the cover art more, it's nice and big without being massive, and most importantly the binding feels a lot sturdier. Then again, if you want something that you can carry around in a bag, the Penguin is probably your best bet as it's about half the size of the Fine.